This is a draft of some practice midterm problems. The level of difficulty here tends to be on the higher side; I would recommend going for mastery of the less difficult problems first. The midterm will not be quite this difficult or this long, but it will be difficult and I expect it to take the full 1hr and 45 min class period. This is just a bunch of problems without detailed design. The midterm will have some straightforward problems and some more difficult ones. Being comfortable with the straightforward problems is very important!
I would like to also mention that there are posts here going back to early January, many of which remain relevant. (They can all be found via the blog archive on the right.) That said, starting problems, working problems and thinking about problems with just bank paper and your one page of notes is the best way to prepare imo. Unless you are stuck on some particular thing, reading produces only an illusion of preparation. In the end you have to be able to solve problems on your own.
Graphing will be featured on the midterm. Also quantum length scales (see problems 5 and 9 below), as well as the calculations of expectation values. Think about the relationship between confinement length scale (position uncertainty) and kinetic energy. Be able to recast the uncertainty principle in terms of a relationship between confinement length (position uncertainty) and kinetic energy.
Here are some partial answers to consider:
5. Well, for the H atom the emergent quantum length scale is ℏ2/[mq2/(4πϵo)]. So what does that tell us? What is it trying to say? Note that the q2/(4πϵo) is in that denominator. That is the strength of the interaction, right? So the stronger the interaction, the smaller the length scale. That q2 is a measure of the strength of the attraction between the electron and proton. The proton is pulling the electron toward it. And the ℏ2, in the numerator, is resisting that. Does that make sense?
For the harmonic oscillator, the emergent quantum length scale is sort of similar in that in depends on [ℏ2/(mk)], where k is a measure of the strength of the HO potential that is trying to confine the electron, and ℏ2 is resisting that (like with H atom). Really the emergent quantum length scale for the 1D HO is, you may recall, a=[ℏ2/(mk)]1/4. Well, I didn't talk about m, but I hope you get the idea.
6. −q2/(4πϵo(4a)), (This minus sign is important.)
Note also that q2/(4πϵo)=1.44eV−nm.
7. To evaluate the K.E., first use k to calculate a, then use a to calculate the K.E..
I may add more later here in terms of commentary or other problems. Please recheck this site
Problem number x2 and x3 are the same problem.
ReplyDeleteThey both ask bout the 1 d H.O.
Thanks. I fixed that.
ReplyDeleteFor number 7,
ReplyDeleteUsing ground state H O function. Is the = [ hbar ^(2) ] / [ 4ma^(2)]
Did anyone else get this?
DeleteI got (3/4) hbar^2/[ma^2]
DeleteI don't think that is quite right. You should get 2 separate terms from taking the derivative. One positive and one negative. take the derivative carefully and check the integrals on wolfram alpha.
Deleteoops, I wrote down my answer for the first excited state H.O.
DeleteFor problem number 8,
ReplyDeleteI got = (16a)/3
I drew some contour maps and I concluded that the overall contour map is is positive in the 4th quadrant. What did everyone else get.
Is my answer correct?
I found a web page that shows the wave functions of the hydrogen atom in 3d. It's pretty cool if anyone wants to check it out! http://www.falstad.com/qmatom/
ReplyDeleteFor the quiz you said our sheet could only be one sided, can it be double-sided for the midterm?
ReplyDeleteno.
DeleteFor question number 8,
ReplyDeleteIs the expectation value of (r) going to be the integration in 3 dimensions of [phi(a) *r phi (a)] dV ?
integration of all 3D space of course.
I was confused if it was (phi(a)) * r * (phi(a))
That's a good guess.
DeleteOww, I get how to do this problem now. Thanks...
DeleteFor 3c what do you mean by "linear combos of psi21x and psi21y"?
ReplyDeletelike .2 psi21x + .3 psi21y is a linear combo.. Doe that make sense?
Deleteyes thank you
DeleteIs it correct to say that the expectation values of potential energy for psi_21x and psi_21z are both equal to zero?
ReplyDeleteno. they are each negative and non-zero.
DeleteI was getting zero when I forgot to square the x, y, or z terms in the wave functions, maybe check to see that you're carrying out your squaring of the wave function correctly and including the (1/r) for PE.
DeleteThe idea here is some problems for you to consider and work on if you like. I will not be posting solutions to these.
ReplyDeleteThe Midterm went well. I am very happy that you posted a midterm review.
ReplyDeleteYou are a very good teacher.